{"id":2833,"date":"2025-05-29T12:54:04","date_gmt":"2025-05-29T17:54:04","guid":{"rendered":"http:\/\/jimlund.org\/blog\/?page_id=2833"},"modified":"2025-08-24T19:52:35","modified_gmt":"2025-08-25T00:52:35","slug":"chemistry-experiments-at-home","status":"publish","type":"page","link":"http:\/\/jimlund.org\/blog\/?page_id=2833","title":{"rendered":"Chemistry experiments at home"},"content":{"rendered":"\n<p><strong>Supply sources<\/strong><\/p>\n\n\n\n<p>alkaline batteries &#8212; Zn metal (case), MnO2, [NH<sub>4<\/sub>]Cl, carbon rod<br>HSO4 &#8211;auto parts stores<\/p>\n\n\n\n<p> <\/p>\n\n\n\n<p><strong>Experiments<\/strong><br>1. Burn Mg metal.<br>2. Electrolysis of H2O -&gt; H2 + O2<br>3. Different color flames (NaCl, )<\/p>\n\n\n\n<p>4. Extract Bismuth Metal from Pepto-Bismol Tablets.  <br>30g pepto-bismo (bismuth subsalicylate) + 260 ml 32% HCl in 1.3 L H2O -&gt; salicylic acid + bismuth chloride -&gt; filter -&gt; bismuth chloride + Al foil -&gt; bismuth (black powder) -&gt; heat in inert atmosphere -&gt; Bi metal<br>5. Li metal from Li battery -&gt; burn.<\/p>\n\n\n\n<p>6. DNA from strawberries<br><br>7. pennies + HCl -> Zn dissolves, laving shell of Cu<\/p>\n\n\n\n<p>8. Thermite: Fe<sub>2<\/sub>O<sub>3<\/sub> + 2 Al \u2192 2 Fe + Al<sub>2<\/sub>O<sub>3<\/sub><\/p>\n\n\n\n<p>9. Red cabbage pH indicator.  Boil red cabbage ~10 min, collect purple juice.  Filter through a paper towel.  The purple color is due to anthocyanins.  These anthocyanins can either accept a proton or donate one, and the three states are three different colors, <a href=\"https:\/\/learn.ddwcolor.com\/why-do-anthocyanins-change-color\/\">link<\/a>, <a href=\"https:\/\/www.instructables.com\/Extracting-Anthocyanin-a-Natural-PH-Indicator\/\">link2<\/a>.  Add test items (colorless or weakly color things work best), and observe.  Used: lime juice, hot sauce, coffee, H2O, baking soda, ammonia. <\/p>\n\n\n\n<p>10. Silver nitrate copper tree.  Silver nitrate solution, 0.1 M.  Suspend copper wire in solution, leave ~10-30 min.  <br>Cu + 2AgNO3 -&gt; 2Ag + Cu(NO3)2.<\/p>\n\n\n\n<p>11. Silver nitrate halide precipitation reactions.  Silver nitrate solution, 0.05 M, Potassium chloride solution, 0.1 M, Potassium iodide solution, 0.1 M, about 1 ml of each.  <a href=\"https:\/\/edu.rsc.org\/experiments\/silver-and-lead-halides\/1770.article\">link<\/a>.<br>AgNO3 + KCl -&gt; AgCl(s) + KNO3<br>Ag<sup>+<\/sup>(aq) &nbsp;+ &nbsp;Cl<sup>&#8211;<\/sup>(aq) &nbsp;<img loading=\"lazy\" decoding=\"async\" width=\"72\" height=\"11\" src=\"https:\/\/www.chemguide.co.uk\/inorganic\/group7\/arrow.gif\"> &nbsp;AgCl(s)<\/p>\n\n\n\n<p>11. Silver nitrate mirror reaction.<\/p>\n\n\n\n<p>Silver nitrate solution, 0.05 M, NaOH 0.0125 M, am\u00admo\u00adnia so\u00adlu\u00adtion 5% &#8211; 10%. Glucose.<br>Mix the so\u00adlu\u00adtion of sil\u00adver ni\u00adtrate and a few milliliters of sodi\u00adum hy\u00addrox\u00adide. A brown sed\u00adi\u00adment of sil\u00adver ox\u00adide forms (2 AgOH \u2192 Ag<sub>2<\/sub>O + H<sub>2<\/sub>O). Then add the am\u00admo\u00adnia un\u00adtil the sed\u00adi\u00adment dis\u00adsolves com\u00adplete\u00adly.  Avoid excess am\u00admo\u00adnia, it can af\u00adfect the qual\u00adi\u00adty off the cov\u00ader\u00ading and the speed at which the sil\u00adver&nbsp;set\u00adtles.  This makes Tollens&#8217; reagent, <a href=\"https:\/\/en.wikipedia.org\/wiki\/Tollens%27_reagent\">link<\/a>.  Add glu\u00adcose so\u00adlu\u00adtion and pour on surface.<br>\u041d\u041e\u0421\u041d\u2082(\u0421\u041d\u041e\u041d)\u2084H\u0421=O (glu\u00adcose) + 2[Ag(NH\u2083)\u2082]OH -&gt; \u041d\u041e\u0421\u041d\u2082(CH\u041e\u041d)\u2084\u0421\u041e\u041eH + 2Ag +4NH\u2083 + 2H\u2082O<br>Better adhesion after stannous chloride rinse.<br><a href=\"http:\/\/www.ilpi.com\/glassblowing\/tutorial_silvering.html\">Link<\/a>, <a href=\"https:\/\/www.thoughtco.com\/silver-ornaments-christmas-project-606131\">link2<\/a>.<br>Aldehyde reaction:<br><img decoding=\"async\" src=\"https:\/\/wikimedia.org\/api\/rest_v1\/media\/math\/render\/svg\/fa6966d8a9edd16842a0b793eb703cb52d441be5\" alt=\"{\\displaystyle {\\ce {2[Ag(NH3)2]+ + R-CHO + H2O -&gt; 2Ag(s) + 4NH3 + R-COOH + 2H+}}}\"> <br>In a positive test, the diamine silver(I) complex oxidizes the aldehyde to a carboxylate ion and in the process is reduced to elemental silver and aqueous ammonia.<\/p>\n\n\n\n<p>Sensitize glass: Stannous chloride 10 g, 20 ml of HCl (0.25 M HCl) in 1 L.<\/p>\n\n\n\n<p>Dissolve 0.45 g AgNO3 in 50 ml H2O.  Add 12.5 ml ammonia, then 2.3 ml of 10 N NaOH.  Then add ammonia until brown precipitate re-dissolves.  Then add 3 g glucose, apply to glass.<\/p>\n\n\n\n<p>12. Sodium polyacrylate, super-absorbent polymer.  <br>Take 30 grams of sodium polyacrylate.  Stir in 400 mL of distilled water.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Supply sources alkaline batteries &#8212; Zn metal (case), MnO2, [NH4]Cl, carbon rodHSO4 &#8211;auto parts stores Experiments1. Burn Mg metal.2. Electrolysis of H2O -&gt; H2 + O23. Different color flames (NaCl, ) 4. Extract Bismuth Metal from Pepto-Bismol Tablets. 30g pepto-bismo (bismuth subsalicylate) + 260 ml 32% HCl in 1.3 L H2O -&gt; salicylic acid + [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-2833","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/pages\/2833","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2833"}],"version-history":[{"count":13,"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/pages\/2833\/revisions"}],"predecessor-version":[{"id":2946,"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/pages\/2833\/revisions\/2946"}],"wp:attachment":[{"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2833"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}