{"id":795,"date":"2017-03-14T14:33:18","date_gmt":"2017-03-14T19:33:18","guid":{"rendered":"http:\/\/jimlund.org\/blog\/?page_id=795"},"modified":"2025-07-15T19:26:55","modified_gmt":"2025-07-16T00:26:55","slug":"ethanol-concentration","status":"publish","type":"page","link":"http:\/\/jimlund.org\/blog\/?page_id=795","title":{"rendered":"Ethanol Concentration"},"content":{"rendered":"\n<p><img loading=\"lazy\" decoding=\"async\" width=\"600\" height=\"300\" class=\"wp-image-2812\" style=\"width: 600px;\" src=\"http:\/\/jimlund.org\/blog\/wp-content\/uploads\/2025\/05\/EtOH_MeOH_spectra.png\" alt=\"EtOH MeOH IR spectra\" srcset=\"http:\/\/jimlund.org\/blog\/wp-content\/uploads\/2025\/05\/EtOH_MeOH_spectra.png 605w, http:\/\/jimlund.org\/blog\/wp-content\/uploads\/2025\/05\/EtOH_MeOH_spectra-300x150.png 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><\/p>\n\n\n\n<p>For Wavenumber \/ \u03bcm conversion, see <a href=\".\/pics\/Raman\/Plyer_1950.pdf\">Plyer, 1953<\/a>.<\/p>\n\n\n\n<p><strong><strong>Methods for determining ethanol concentration in water.<\/strong><br><\/strong><\/p>\n\n\n\n<p><strong>Raman spectroscopy<br><\/strong>General info about specs: https:\/\/kpu.pressbooks.pub\/organicchemistry\/chapter\/6-3-ir-spectrum-and-characteristic-absorption-bands\/<\/p>\n\n\n\n<p>Simple \/ DIY versions:<\/p>\n\n\n\n<p><strong>NIR gas analysis<\/strong><br>Paper on measuring ethanol from head gas, <a href=\"pics\/260260418_ftp.pdf\">link<\/a>. Uses a Binos 100 gas analyzer, see the <a href=\"pics\/manual--binos-100-series-analyzers-including-oxynos-100--hydros-100-and-cat-100---software-version-5-1x---4th-ed--data.pdf\">manual<\/a>, principal of operation on p59-60. Uses two interference filters, one for ethanol absorbance region (4300nm), other for reference (4000nm) where no absorbance is expected.<\/p>\n\n\n\n<p>Intoxilyzer&#8211;Lion Labs \/ CMC, <a href=\".\/pics\/Raman\/Intoxilyzer_spec04.pdf\">specs<\/a><\/p>\n\n\n\n<p>An IR emitter shines in chamber w\/ gas, 3.4 um and 9.34 um bandpass detectors are outside, sense through plastic cover.<br>Bandpass detectors:<\/p>\n\n\n\n<p>9.50 \u03bcm, 400 nm BW, USEQGSEH950180, $13<br>3.30 \u03bcm, 130 nm BW, USEQGSEACH4180, $15<br>3.91 \u03bcm, 90 nm BW, USEQFSEA391180, $14<br>Kemet range of IR sensors, 1-4 channels, https:\/\/www.kemet.com\/en\/us\/sensors\/environmental-sensors\/gas-detection.html, also .\/pics\/Raman\/KEM_SE0215_QDC-3316800.pdf<\/p>\n\n\n\n<p><strong>FTIR liquid analysis<\/strong><br>Using <a href=\"https:\/\/en.wikipedia.org\/wiki\/Attenuated_total_reflectance\">ATR<\/a> with a zinc selenide crystal. ZnSe crystals are farily expensive and hard to source.<\/p>\n\n\n\n<p>This usually is a infrared spectroscopy technique, so a diffraction grating is necessary and moving parts to scan over the frequency range. This reduces source light intensity and increases complexity. The solution is more general.<\/p>\n\n\n\n<p><a href=\"pics\/2014_FTIR_Lab.pdf\">College lab in FTIR<\/a><\/p>\n\n\n\n<p>IR LED system patent using a tunable IR dichromic \/ interference filter: <a href=\"https:\/\/www.google.com\/patents\/DE19849847A1?cl=en\">link<\/a>. This filter is expensive and hard to source.<\/p>\n\n\n\n<p>Use one or more IR diodes to measure IR adsorption by ethanol<br>IR LED, 4200nm, 0.010 mW Quasi-CW, 0.2 mW Pulsed, <a href=\"https:\/\/www.thorlabs.com\/thorproduct.cfm?partnumber=LED4300P\">$70<\/a><br>LED43 10 \u03bcW (200 \u03bcW Pulsed), TO18, <a href=\"http:\/\/ir.microsensortech.com\/leds.htm\">$37.5<\/a>. Broad spectrum 3000-5000nm.<\/p>\n\n\n\n<p>Mid IR filters, 500 nm range <a href=\"https:\/\/www.thorlabs.com\/newgrouppage9.cfm?objectgroup_id=5871\">$315<\/a>; narrow bandpass, <a href=\"https:\/\/www.iridian-optical-filters.com\/product-category\/mid-ir-bandpass\/\">$265<\/a><\/p>\n\n\n\n<p><strong>Enzymatic \/ fluorescent<\/strong><br><a href=\"pics\/ethanol.pdf\">College chem lab<\/a><\/p>\n\n\n\n<p><\/p>\n\n\n\n<p>Related item, precision CO2 sensor using NDIR, <a href=\"https:\/\/www.aliexpress.com\/item\/Free-shipping-MH-Z19-CO2-Carbon-dioxide-gas-sensor-serial-output-5000ppm-non-dispersive-infrared\/32651094869.html?aff_platform=product&amp;cpt=1496088548891&amp;sk=ufe2zVf&amp;aff_trace_key=2b52ae10ce004a34bb35fe22e57687dd-1496088548891-02893-ufe2zVf\">$60<\/a><br>MH-Z19 carbon dioxide gas sensor (hereinafter referred to as the sensor) is a generic type, small sensors, using non dispersive infrared (NDIR) principle to detect the air in the presence of CO2, with good selectivity and no oxygen dependence and long service life. Built in temperature compensation, with digital output and waveform output, easy to use. The sensor is a high performance sensor which is combined with the mature infrared absorption gas detection technology and the precise optical path design and the excellent circuit design.<br><br>Cell phone Raman spetrophotometer<br><br>collimating lens used in the spectrometer was \u223c25 mm in diameter, with a 60 mm focal length<br>Related item, precision CO2 sensor using NDIR, <a href=\"https:\/\/www.aliexpress.com\/item\/Free-shipping-MH-Z19-CO2-Carbon-dioxide-gas-sensor-serial-output-5000ppm-non-dispersive-infrared\/32651094869.html?aff_platform=product&amp;cpt=1496088548891&amp;sk=ufe2zVf&amp;aff_trace_key=2b52ae10ce004a34bb35fe22e57687dd-1496088548891-02893-ufe2zVf\">$60<\/a><br>MH-Z19 carbon dioxide gas sensor (hereinafter referred to as the sensor) is a generic type, small sensors, using non dispersive infrared (NDIR) principle to detect the air in the presence of CO2, with good selectivity and no oxygen dependence and long service life. Built in temperature compensation, with digital output and waveform output, easy to use. The sensor is a high performance sensor which is combined with the mature infrared absorption gas detection technology and the precise optical path design and the excellent circuit design.<br><br>Cell phone Raman spetrophotometer<br><br>collimating lens used in the spectrometer was \u223c25 mm in diameter, with a 60 mm focal length<br>lens (\u223c10 mm focal length and 4 mm diameter)<\/p>\n","protected":false},"excerpt":{"rendered":"<p>For Wavenumber \/ \u03bcm conversion, see Plyer, 1953. Methods for determining ethanol concentration in water. Raman spectroscopyGeneral info about specs: https:\/\/kpu.pressbooks.pub\/organicchemistry\/chapter\/6-3-ir-spectrum-and-characteristic-absorption-bands\/ Simple \/ DIY versions: NIR gas analysisPaper on measuring ethanol from head gas, link. Uses a Binos 100 gas analyzer, see the manual, principal of operation on p59-60. Uses two interference filters, one for [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"open","ping_status":"open","template":"","meta":{"footnotes":""},"class_list":["post-795","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/pages\/795","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=795"}],"version-history":[{"count":7,"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/pages\/795\/revisions"}],"predecessor-version":[{"id":2868,"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=\/wp\/v2\/pages\/795\/revisions\/2868"}],"wp:attachment":[{"href":"http:\/\/jimlund.org\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=795"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}